Journal of Oil Palm Research Vol. 21  2009 June p.  613-620
DOI:

Solid-state characteristics of microcrystalline cellulos from oil palm empty fruit bunch fibre

Author(s): ROSNAH Mat Soom* ; ASTIMAR Abd Aziz* ; WAN HASAMUDIN Wan Hassan* ; AB GAPOR Md Top*

Oil palm empty fruit bunches (EFB) are one of the by-products generated from palm oil mills. They consist mainly of lignocellulosic compounds, namely cellulose, hemicellulose and lignin. Cellulose, in particular, constitutes about 37% (dry weight) of the EFB, and is a compound with high value and can be exploited for the benefit of the palm oil industry.
In this study, an attempt to prepare microcrystalline cellulose (MCC) from the isolated EFB-cellulose was carried out. The MCC was prepared by controlled acid hydrolysis of the isolated a-cellulose which attacked the amorphous region, and was followed by the back neutralization process with alkali. The structural properties of the cellulose and MCC were studied by Fourier Transformed Infra-red Spectrometry (FTIR) and X-ray diffraction methods. The FTIR spectrum of MCC from EFB was identical to that of the commercial MCC as well as the cellulose which showed comparable presence of C-O-C, C-C, O-H, and C-H bands. However, a broad peak at 3329 cm-1 was observed from the EFB-cellulose due to absorption vibration of the hydroxyl groups. The X-ray diffraction pattern revealed a low degree of order for EFB-cellulose and a relatively ordered structure for EFB-MCC. Two peaks of diffraction angles ranging between 19º and 23º were observed in the EFB-MCC, indicating the presence of a small percentage of cellulose II. The commercial MCC had a highly ordered structure compared to EFB-MCC as indicated by the presence of a single peak at 22.5º.

Keywords: , , ,

Author Information
* Malaysian Palm Oil Board, P. O. Box 10620, 50720 Kuala Lumpur, Malaysia.
E-mail: astimar@mpob.gov.my


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