RESEARCH ARTICLE

Journal of Oil Palm Research Vol. 35 (4) December 2023, p. 639-652

THERMAL ANALYSIS AND NON-ISOTHERMAL THERMOGRAVIMETRIC KINETICS ANALYSIS USING COATS-REDFERN METHOD OF A TORREFIED EMPTY FRUIT BUNCHES

MOHAMAD AZRI SUKIRAN1*; PETER ADENIYI ALABA2; ABU BAKAR NASRIN1; ASTIMAR ABDUL AZIZ1 and SOH KHEANG LOH1

DOI: https://doi.org/10.21894/jopr.2023.0011
Received: 28 June 2022   Accepted: 8 January 2023   Published Online: 9 March 2023
ABSTRACT

Thermal and mechanistic behaviours of solid biofuel are essential for commercial exploitation. In this work, the suitability of torrefied EFB as a solid biofuel was evaluated by investigating its physicochemical characteristics, kinetics and reaction mechanism during pyrolysis. The pyrolysis behaviour of raw and torrefied EFB was predicted via thermogravimetric analysis, kinetic parameters via Coats-Redfern three pseudo-components model-fitting method and pyrolysis mechanism via Criado method with Z-master plot. The physicochemical properties of torrefied EFB improved significantly compared to raw EFB in terms of fuel properties such as carbon content (8%-41%), fixed carbon (79%-328%) and calorific value (7%-42%). The degradation rate of hemicellulose and cellulose of torrefied EFB increased when the torrefaction temperature increased from 225°C to 300°C, leading to lower char yield and overall activation energy to initiate the pyrolysis process. The model deduced that higher overall activation energy was exhibited by raw EFB (9.39 kJ/mol) than those of torrefied EFB ranging from 6.55-7.86 kJ/mol (300°C-225°C). Thermal degradation of hemicellulose from torrefied EFB dominated the process by about 74% compared to cellulose and lignin when torrefaction temperature increased from 225°C to 300°C. Torrefaction could convert the power law mechanism to nucleation and growth mechanism gradually, allowing for better EFB thermal decomposition as a whole.

KEYWORDS:


1 Malaysian Palm Oil Board,
6 Persiaran Institusi, Bandar Baru Bangi,
43000 Kajang, Selangor, Malaysia.

2 Department of Chemical Engineering,
Faculty of Engineering, University of Malaya,
50603 Kuala Lumpur, Malaysia.

* Corresponding author e-mail: azri@mpob.gov.my