Journal of Oil Palm Research Vol. 10 No. 1, June 1998, p. 1-14
HYDROXYSTEARIC COMPOUNDS FROM UNSATURATED PALM FATTY ACID
Initial studies on hydroxylation of unsaturated palm fatty acids were carried out with very promising results. Hydroxylation of unsaturated palm fatty acids with hydrogen peroxide-acetic acid for two hours gave products with melting points of 79°C – 128°C, acid values of 135-165, saponifiable values of 119-128 and hydroxyl values of 384-440. Yield of the product was about 80% – 90%. The product characteristics were very different from those obtained from other oils. For example, hydroxy fatty acid from sunflower oil has a saponifiable value of 212, acid value of 140 and hydroxyl value of 222 (Dahlke et al., 1995).
The product obtained in this study was not only 9,10-dihydroxystearic acid but also some fatty acids and 10-oxo-stearic acid. By adding hydroxystearic acid at a concentration of 0.2%, the life of steel was extended by up to 10 times, showing that hydroxystearic acid was very effective as a rust inhibitor. Therefore, hydroxylation of unsaturated palm fatty acid is a promissing process for obtaining hydroxystearic compounds.
KEYWORDS:* Department of Chemical and Process Engineering,
Faculty of Engineering,
Universiti Kebangsaan Malaysia,
43600 UKN Bangi, Selangor, Malaysia
** Indonesian Oil Palm Research Institute (IOPRI),
O.O Box 1103, Medan 20001, Indonesia.